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O **número quântico magnético (ml)** descreve a orientação do orbital de um elétron no espaço. Os valores de *ml* variam de -l a +l, incluindo 0. Cada valor de *ml* corresponde a uma orientação diferente do orbital no espaço. Por exemplo, para um orbital p (l=1), existem três possíveis valores de *ml*: -1, 0 e +1, que correspondem a três orientações diferentes do orbital no espaço. A presença de um campo magnético externo pode afetar a energia dos elétrons, dependendo da orientação do orbital. Essa interação é a base de fenômenos como o efeito Zeeman, que causa a divisão das linhas espectrais de um átomo em um campo magnético. O número quântico magnético é essencial para entender como os átomos interagem com campos magnéticos e como a luz interage com a matéria.
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